Tetrasubstituted Allene Ethers; Synthesis and Use in Nazarov Reactions

Bradley K. Tokeshi; Marcus A. Tius

doi:10.1055/s-2004-815994

SPECIALTOPIC

Tetrasubstituted Allene Ethers; Synthesis and Use in Nazarov Reactions

Bradley K. Tokeshi, Marcus A. Tius*
2545 The Mall, University of Hawaii, Honolulu, Hawaii 96822, USA
e-Mail: tius@gold.chem.hawaii.edu;

Abstract

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Abstract

A method for the synthesis of tetrasubstituted allene ethers is described, making use of a reverse Brook rearrangement in the key step. The allene products have been used in the Nazarov cyclization reaction.

Key words

allenes - Nazarov reactions - ethers - rearrangements - alkynes - cyclizations

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Referenzen

References

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